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41.
辽东半岛古元古界辽河群大石桥组三段地层中赋存有全球最大工业储量的菱镁矿矿床。在总结和整理已发表的辽东半岛晶质菱镁矿床地质和地球化学数据的基础上,本次研究进行了Mg和B同位素测试及研究工作,获得以下认识:① 菱镁矿矿体呈北东东走向,产于大石桥组三段,但不同矿床的矿体厚度差异较大 (30~300 m),菱镁矿矿体与顶、底板高镁白云岩之间以断层接触为主,常可见到绿泥石化板岩和碳质千枚岩产于大型菱镁矿矿体的内部韧性剪切面上,说明地层经历了强烈构造形变作用;② 围岩白云岩与晶质菱镁矿矿石的地球化学特征基本一致,均表现为大离子亲石性元素(K、Rb、Ba、Sr等)亏损和氧同位素负漂移(δ18O:-24. 9‰~-11. 0‰);③在经历构造形变和角闪岩相变质作用后,菱镁矿矿石仍继承有海相蒸发沉积岩的稳定同位素地球化学特征(δ13C:-2. 7‰~+1. 6‰;δ34S:+15. 6‰~+23. 7‰;δ26Mg:-1. 53‰~-0. 49‰;δ11B:+9. 8‰~+13. 4‰);④ 后期裂控型滑石具有相对较高的δ26Mg值(-0. 32‰~-0. 15‰),发生滑石矿化的菱镁矿(δ11B:+7. 7‰~+8. 4‰)和围岩变粒岩(δ11B:+4. 3‰)显示较低的δ11B值,这反映了变质热液作用所引发的Mg和B同位素分馏现象。因此,辽东半岛海城- 大石桥地区菱镁矿矿床镁质富集的根本原因可能为潟湖相沉积碳酸盐岩经准同生阶段的富镁卤水交代所致,非后期变质热液交代作用的结果。  相似文献   
42.
柴达木盆地西部南翼山地区深层卤水是经济价值极高的液体矿床,以富含钾、硼、锂和溴等为特征,前人认为南翼山背斜构造区地层的岩性控制着深层富钾卤水的分布。本次研究结果认为,该区卤水主要受控于背斜构造中发育的断层裂隙,深度范围为上新统上油砂山组至渐新统下干柴沟组。本文着重以青藏高原柴达木盆地西部南翼山背斜构造E3g–N1y地层富钾深层卤水的形成机制及水化学特征为研究对象,在野外观察、取样及室内分析的基础上,综合分析地质及石油等相关部门地质、水文、物探等方面资料,及对青海油田公司老井最新的卤水层射孔资料,结合储卤层沉积环境、地质构造,富钾深层卤水水文地质及地球化学特征,认为柴达木盆地西部南翼山背斜构造从渐新世至上新世经历了深湖相—半深湖相—浅湖相—潮坪相沉积。沉积环境决定着原始深层卤水的水性与水质,南翼山背斜褶皱构造形成的同时,产生了一系列纵向、横向及顺层等断层及相应的构造裂缝(隙),构成了富钾深层卤水的储水空间。大量的化学分析资料显示,南翼山背斜构造区深层卤水是封闭程度高的还原环境下沉积变质作用的产物。  相似文献   
43.
正Polyhalite(K2SO4·Mg SO4·2Ca SO4·2H2O)is one of the insoluble potassium mineral which is widely distributed in sulfate-type potassium-bearing deposit,and the theoretical concentration of K2SO4 is 28%.It can be directly used as a  相似文献   
44.
正It is a major continuous depocenter in Dalangtan area,western Qaidam basin since Early Cenozoic,which is most important Neogene salt deposits center in Qaidam basin.The Miocene Saline lake was developed firstly in  相似文献   
45.
We present results of a comprehensive study of ground ice, saline waters, and brines in the cryoartesian basins of the northeastern Siberian Platform. The composition of major geochemical types of ground ice is considered. The specifics of the hydrogeochemical zonation of the cryoartesian basins are the regional distribution of chloride saline waters and brines. Study of stable isotopes (18O, D, 37Cl, 81Br, and 87Sr/86Sr) led us to the conclusion that the chloride brines resulted either from the leaching of halogen rocks or from the metamorphism of bittern connate water. The drainage brine reserves (hydromineral resources) of the Udachnaya kimberlite pipe in the Olenek cryoartesian basin are assessed.  相似文献   
46.
江汉盆地潜江凹陷潜江组赋存有丰富的地下卤水,因其有较高的经济价值,是江汉盆地油气资源之外的又一种重要的战略资源。然而,长期的油田注水开采也对地下卤水产生了一定的影响,为进一步评估这种影响并探讨地下卤水微量元素的分布情况,通过采集和分析潜江组第一至第四卤水组的地下卤水样品开展其地球化学特征和分布规律的研究。结果表明,潜江凹陷潜江组地下卤水受油田生产影响,虽然普遍发生了淡化,但仍然拥有较高的TDS含量,淡化影响有限。卤水储层从上至下,第一卤水组至第四卤水组,随着深度的增加,硫酸钠亚型卤水和碳酸盐型水逐渐变少,氯化物型水逐渐增多。尽管区内地下卤水普遍经受油田注水生产的影响,但是卤水中Li、B、Br等元素依然保持较高的含量,大部分样品达到或超过边界工业品位,尤其以第二、第三卤水Li、B、Br品位较高,第四卤水组次之,第一卤水组最低。潜江凹陷地下卤水样品的钠氯系数接近于1,具备溶滤卤水特征,属于非海相地层的卤水,氯溴系数分析揭示区内现存地下卤水是溶滤卤水和沉积卤水混合以后的结果,卤水的脱硫系数和钙镁系数反映卤水的储集空间封闭性相对较差,凹陷内从第一至第三下卤水储集体的空间的封闭性逐渐变好,第四卤水组略变差。平面上,Li、B、Br具有相似的分布特征,凹陷内,卤水的浓集中心从下至上具有明显的迁移特征,钟市、浩子口、王场、周矶所围限的区域是高浓度卤水分布中心地带,其分布明显受控于卤水储集体的分布。  相似文献   
47.
莱州湾南岸地下卤水高浓度溶解铀及其成因研究   总被引:1,自引:0,他引:1  
用α能谱法对莱州湾南岸地下卤水中的铀进行分析,发现卤水中溶解铀的浓度范围为3.4~96.0μg/L,80%以上站位卤水铀浓度超过了30μg/L,高于某些铀矿区地下水中铀的浓度。从卤水的形成过程及环境、含水层沉积物的铀含量及地下卤水对沉积物的淋溶作用、地表水下渗等几个方面对高浓度铀的成因进行了分析,发现卤水形成时海水的蒸发浓缩和锰氧化物还原可能是主要成因,藻类的矿化分解使其吸附的大量铀解吸进入地下水也可能是1个重要影响因素。  相似文献   
48.
Interaction of metalliferous continental brines with biogenic sulphide is the basis of some syngenetic and early diagenetic models for the formation of Cu‐(Pb‐Zn) sulphides during a depositional cycle of carbonates in restricted marine environments. A variation of these models (an ‘evaporative concentration‐lateral groundwater flow’ model) is proposed, using hydrological, geochemical and biological data from low metal, but otherwise pertinent redbed‐associated, sabkha, tidal flat and subtidal environments at Nilemah Embayment, in Hamelin Pool (Shark Bay, Western Australia).

The model is constrained by: (i) the short time available for ore accumulation during a single depositional cycle; (ii) limitation of adequate rates of bacterial sulphate reduction for the formation of an ore deposit to near‐surface sediments; (iii) restriction of the most favourable ore‐forming sites to the intertidal zone and the littoral shelf; (iv) coincidence in these sites of laterally‐flowing marine/meteoric groundwater brine, and mosaics of in situ cyanobacterial mats and shallow erosional depressions containing detrital organic matter eroded from the mats. Under these conditions the metalliferous fluid would have to contain about 1000 ppm Cu and flow for 1000 years at a rate of 5 m/a through the intertidal/littoral shelf environment to produce an ore deposit.

Critical features of a model that could generate this combination of very high metal concentrations and flow rates are: (i) a highly permeable unconfined aquifer system comprising alluvial fans at the base of basaltic mountain ranges and continental redbeds beneath a broad coastal plain; (ii) mobilization, concentration and transport of the metals in this aquifer to intertidal/littoral shelf sites of ore deposition; (iii) effective concentration processes in the aquifer, involving evaporation and reflux of brines in groundwater discharge areas on the coastal plain and evaporation in marine‐continental and marine sabkhas bordering the sites of deposition; (iv) rapid lateral groundwater flow of the concentrated metalliferous brines under a strong seawards‐directed hydraulic gradient; and (v) discharge of the metalliferous brines into or through topographic depressions generated by erosion and shoaling in the peritidal and littoral shelf environments.

The model hydrodynamic processes and their magnitude are within the range observed in modern environments but they are most likely to be effective in coarse‐grained, topographically irregular carbonate sabkhas and tidal flats, which usually form under high‐energy conditions. Even under these conditions, the individual ore‐forming processes must combine in an optimum manner before the highly demanding metal concentrations and flow rates required for ore formation in a single marine depositional cycle can be met.  相似文献   
49.
http://www.sciencedirect.com/science/article/pii/S1674987112000394   总被引:1,自引:0,他引:1  
High-grade dehydration of amphibolite-facies rocks to granulite-facies is a process that can involve partial melting,fluid-aided solid-state dehydration,or varying degrees of both.On the localized meter scale,solid-state dehydration,due to CO2-rich fluids traveling along some fissure or crack and subsequently outwards along the mineral grain boundaries of the surrounding rock,normally is the means by which the breakdown of biotite and amphibole to orthopyroxene and clinopyroxene occur.Various mineral textures and changes in mineral chemistry seen in these rocks are also seen in more regional orthopyroxene-clinopyroxene-bearing rocks which,along with accompanying amphibolite-facies rocks, form traverses of lower crust.This suggests that solid-state dehydration during high-grade metamorphism could occur on a more regional scale.The more prominent of these fluid-induced textures in the granulitefacies portion of the traverse take the form of micro-veins of K-feldspar along quartz grain boundaries and the formation of monazite inclusions in fluorapatite.The fluids believed responsible take the form of concentrated NaCl- and KC1- brines from a basement ultramafic magma heat source traveling upwards along grain boundaries.Additional experimental work involving CaSO4 dissolution in NaCl-brines. coupled with natural observation of oxide and sulfide mineral associations in granulite-facies rocks,have demonstrated the possibility that NaCl-brines,with a CaSO4 component,could impose the oxygen fugacity on these rocks as opposed to the oxygen fugacity being inherent in their protoliths.These results, taken together,lend credence to the idea that regional chemical modification of the lower crust is an evolutionary process controlled by fluids migrating upwards from the lithospheric mantle along grain boundaries into and through the lower crust where they both modify the rock and are modified by it. Their presence allows for rapid mass and heat transport and subsequent mineral genesis and mineral reequilibration in the rocks through which they pass.  相似文献   
50.
川西地区雷口坡组岩相古地理与富钾卤水预测   总被引:3,自引:1,他引:2  
利用测井、录井、岩芯、薄片、扫描电镜及能谱分析等资料,综合研究川西地区雷口坡组岩相古地理、分析富钾卤水成因并预测有利分布区带。川西地区中三叠统雷口坡组发育蒸发台地相、局限台地相和开阔台地相。地层年代从古到新可分为雷一至雷五共5期,海平面经历了2次变浅→加深的旋回,雷四1期由于快速海退,广泛发育蒸发台地相,其中成都地区膏盆内发育平落坝、盐井沟及大兴场3个盐盆。认为川西地区雷口坡组富钾卤水是由海水蒸发浓缩而成的海相原生沉积含钾卤水,在晶间卤水、钾盐类溶滤水和陆相径流来源卤水的掺合下,发生高度变质作用而形成的混合型水。富钾卤水遵循"膏盆-盐盆控区、褶皱-断层定带、裂缝-孔隙储卤"的分布特征。在沉积相、岩相古地理、富钾卤水来源与分布特征等综合研究的基础上,提出了"卤水聚钾中心"和"储卤中心"的概念,结合单井卤水层水化学分析数据与富钾卤水的工业开采指标,在川西地区雷口坡组圈定并预测出1个卤水聚钾中心和3个储卤中心;卤水聚钾中心位于平落坝构造区,储卤中心分别位于江油中坝、丹棱大兴场以及彭山盐井沟构造区,可为四川盆地中三叠统雷口坡组富钾卤水的勘探指明方向。  相似文献   
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